Silicon (Si)-based materials have emerged as promising alternatives to graphite anodes in lithium-ion (Li-ion) batteries due to their exceptionally high theoretical capacity.
3 天之前· Formulating an electron beam-induced covalently interconnected network with silicon anode material and gel polymer electrolyte can benefit high-energy LIB electrodes with next
The biomimetic design provides a new approach to develop functional binder for high-performance battery materials with huge volume deformation, and may promote the
2 天之前· The use of SSEs opens new possibilities for advancement of novel electrode materials and battery pack assembly, and it arguably mitigates some of the safety risks of conventional
Silicon-based anode materials possess exceptionally high specific capacity, hence facilitating the achievement of high energy density in lithium-ion batteries, as they are considered the best
Silicon-based anode materials for Li ion batteries may be broadly classified into three categories: silicon oxides (SiO), silicon–carbon composites and silicon-based alloys.
Silicon has attracted attention as a high-capacity material capable of replacing graphite as a battery anode material. However, silicon exhibits poor cycling stability owing to
As one of the highest specific capacity anode materials in lithium-ion batteries, the main technical issue for silicon (Si) based electrodes is the rapid capacity fading caused by
High-capacity silicon (Si) electroactive materials are actively explored to develop practical lithium-ion batteries (LIBs). Unfortunately, they suffer from structural instability at the material and
For example, preparing nano-porous silicon and uniformly mixing it with sulfide electrolyte and conductive carbon to prepare a composite anode could alleviate volume
As one of the highest specific capacity anode materials in lithium-ion batteries, the main technical issue for silicon (Si) based electrodes is the rapid capacity fading caused by the huge volume changes. Porous Si materials are reported to efficiently alleviate the side effects of volume fluctuation.
Silicon (Si), the second-largest element outside of Earth, has an exceptionally high specific capacity (3579 mAh g −1), regarded as an excellent choice for the anode material in high-capacity lithium-ion batteries. However, it is low intrinsic conductivity and volume amplification during service status, prevented it from developing further.
Silicon-based/carbon batteries with different material structure, binder, and electrolyte designs. Si/C composites can enhance both the mechanical stability and capacity of the anodes when compared with bulk Si anodes.
Currently, silicon-based anode materials are mixed 8–12% with graphite to enhance the energy density of the cell. To gain more energy, silicon needs to become dominant in the anode: for example, >50% (ref. 26).
The performance of electrolytes with silicon-based anodes. Severe volume expansion during the lithiation and de-lithiation process of Si particles, low intrinsic conductivity and slow ion diffusion, and the unstable solid–electrolyte interfaces significantly inhibited the further improvement in the performance of the Si-based materials.
However, the low-cost micro-silicon materials are always criticized and discarded in batteries due to the severe particle-to-electrode crack and huge volume change. Herein, inspired by the human ligament, a cross-linked binder with greatly enhanced mechanical properties is designed and fabricated to stabilize micro-silicon anodes.
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